略歴
2001	近畿大学大学院総合理工学研究科 物質系工学専攻　博士前期課程　修了
2004	奈良先端科学技術大学院大学物質創成科学研究科 物質創成科学専攻　博士後期課程　修了
2004-2007	（独）産業技術総合研究所　博士研究員
2007-2010	（独）理化学研究所基幹研究所 分子情報生命科学研究推進グループ　協力研究員 九州大学大学院工学研究院 分子情報連携研究センター　博士研究員（兼任）
2010-2015	(財)九州先端科学技術研究所 ナノテク研究室 研究員 九州大学 未来科学創造センター 客員助教
2015-	九州大学　最先端有機光エレクトロニクス研究 センター　学術研究員
学位
博士（工学）（奈良先端大、2004年）
所属学会
日本化学会、高分子化学会、シクロデキストリン学会
研究分野
超分子化学（界面化学、生体関連化学、複合材料化学、高分子化学、構造化学など）
趣味
ドライブ、カメラ、酒、肴

研究成果

論文発表

[35]

Tailoring of the desired selectivity and the turn-on detection range in a self-assembly-based fluorescence sensory system
Chem. Sci., (in press)
T. Noguchi, B. Roy, D. Yoshihara, Y. Tsuchiya, T. Yamamoto, S. Shinkai*

[34]

One-pot Optical Sensing of Keto Acids through a Combination of Oxime-click Reaction and Aggregation-induced Emission (AIE)
Chem. Lett, (in press)
D. Yoshihara, T. Noguchi, Y. Tsuchiya, B. Roy, T. Yamamoto, S. Shinkai*

[33]

Molecular recognition directed supramolecular control over perylene-bisimide aggregation resulting in aggregation induced enhanced emission (AIEE) and induced chiral amplification
J. Mater. Chem. C, 3, 2310-2318 (2015)
B. Roy, Y. Tsuchiya, T. Noguchi, D. Yoshihara, T. Yamamoto, S. Shinkai*
DOI:10.1039/C4TC02538E

[32]

Translation of Dicarboxylate Structural Information to Fluorometric Optical Signals through Self-Assembly of Guanidinium-Tethered Oligophenylenevinylene
Chem. Eur. J., 20, 13938-13944 (2014)
T. Noguchi, B. Roy, Y. Tsuchiya, D. Yoshihara, T. Yamamoto, S. Shinkai*
DOI: 10.1002/chem.2014404028

[31]

Cyclization-Induced Turn-On Fluorescence System Applicable to Dicarboxylate Sensing
Chem. Eur. J., 20, 381-384 (2014)
T. Noguchi, B. Roy, D. Yoshihara, Y. Tsuchiya, T. Yamamoto, S. Shinkai*
[Chemistry Views highlight (Wiley-VHC).]
DOI: 10.1002/chem.201304031

[30]

Nucleotide Sensing with a Perirene-based Molecular Receptor via Amplified Fluorescence Quenching
Org. Biomol. Chem., 12, 561-565 (2014)
B. Roy, T. Noguchi, D.Yoshihara, Y. Tsuchiya, T. Yamamoto, S. Shinkai*
DOI: 10.1039/C3OB41586D

[29]

Creation of Circularly Polarized Luminescence from an Achiral Polyfluorene Deriivative through Complexation with Helix-forming Polysaccharides: Important of the meta-Linkage Chain for Heliix formation
Chem. Asian J., 9, 218-222 (2014)
T. Shiraki, Y. Tsuchiya, T. Noguchi, S. Tamaru, N. Suzuki, M. Taguchi, M. Fujiki, S. Shinkai*
DOI: 10.1002/asia.201301216

[28]

Cyclodextrin-Assisted Synthesis of a Metallosupramolecular Tb(III) Polymer and Its Fluorescence Properties and Chiral Recognition
Chem. Eur. J. 19, 15485-15488 (2013)
D. Yoshihara, Y. Tsuchiya, T. Noguchi, T. Yamamoto, S. Shinkai*
DOI: 10.1002/chem.201302138

[27]

Dye-sensitized Preparation of Chiral Plasmonic Ag Nanoparticles on Helical Polysaccharides
Supramol. Chem., 25, 748-755 (2013)
Y. Tsuchiya*, T. Noguchi, D. Yoshihara, T. Yamamoto, T. Shiraki, S. Tamaru, S. Shinkai*
DOI: 10.1080/10610278.2013.835049

[26]

Selective Detection of NADPH among Four Pyridine-Nucleotide Cofactors by a Fluorescent Probe Based on Aggregation-Induced Emission
Macromol. Rapid Commun, 34, 779-784 (2013)
T. Noguchi, A. Dawn, D. Yoshihara, Y. Tsuchiya, T. Yamamoto, S. Shinkai*
[Materials Views (Wiley-VHC).]
DOI: 10.1002/marc.201300015

[25]

Nonlinear Fluorescence Response Driven by ATP-induced Selfassembly of Guanidium-tethered Tetraphenylethene
Chem. Commun, 48, 8090-8092 (2012)
T. Noguchi, T. Shiraki, A. Dawn, Y. Tsuchiya, T. N. L. Le, T. Yamamoto, S. Shinkai*
[Selected as Newsworthy Chemistry (ACS).]
DOI: 10.1039/c2cc33262k

[24]

Unexpected Chiral induction from achiral cationic polythiophene aggregates and its application to the sugar pattern recognition
Chem. Commun, 48, 7091-7093 (2012)
T. Shiraki, A. Dawn, Y. Tsuchiya, T. Yamamoto, S. Shinkai*
DOI: 10.1039/c2cc33162d

[23]

Creation of Chiral Thixotropic Gels through a Crown-Ammonium Interaction and Their Application to a Memory-Erasing Recycle System
Chem. Eur. J., 18, 2832-2838 (2012)
A. A. Sobczuk, Y. Tsuchiya, T. Shiraki, S. Tamaru, S. Shinkai*
DOI: 10.1002/chem.201103249

[22]

Stereochemistry Dependent, Mechanoresponsive Supramolecular Host Assemblies for Fullerenes: A Guest Induced Enhancement of Thixotropy
J. Am. Chem. Soc., 134, 2161-2171 (2012)
A. Dawn, T. Shiraki, H. Ichikawa, A. Takada, Y. Takahashi, Y. Tsuchiya, T. N. L. Le, S. Shinkai*
DOI: 10.1021/ja211032m

[21]

Fine Wettability Control Created by a Photochemical Combination Method for Inkjet Printing on Self-Assembled Monolayers
Adv. Mater., 24, 968-972 (2012)
Y. Tsuchiya, S. Haraguchi, M. Ogawa, T. Shiraki, H. Kakimoto, O. Gotou, T. Yamada, K. Okumoto, S. Nakatani, K. Sakanoue, S. Shinkai*
DOI: 10.1002/adma.201104277

[20]

Supramolecular Dye Inclusion Single Crystals Created from 2,3,6-Trimethyl-β-cyclodextrin and Porphyrins
Chem. Eur. J., 18, 456-465 (2012)
Y. Tsuchiya*, T. Shiraki, T. Matsumoto, K. Sugikawa, K. Sada, A. Yamano, S. Shinkai*
[Selected as Frontispiece.]
DOI: 10.1002/chem.201102075

[19]

Heat and light dual switching of a single walled carbon nanotube/thermo-responsive helical polysaccharide complex: a new responsive system applicable to photodynamic therapy
Chem. Commun, 47, 7065-7067 (2011)
T. Shiraki, A. Dawn, T. N. L. Le, Y. Tsuchiya, S. Tamaru, N. Enomoto, J. Hojo, S. Shinkai*
DOI: 10.1039/C1CC11288K

[18]

A pH-responsive carboxylic β-1,3-glucan polysaccharide for complexation with polymeric guests
Org. Biomol. Chem. 9, 4266-4275 (2011)
T. N. L. Le, T. Shiraki, A. Dawn, Y. Tsuchiya, D. Tokunaga, S. Tamaru, N. Enomoto, J. Hojo, S. Shinkai*
DOI: 10.1039/C1OB05114H

[17]

Facile Fabrication of CD-Active One Dimensional Polypyrrole by the Templating Effect of Helix-Forming Anionic Polysaccharide
Supramol. Chem., 23, 239-243 (2011)
K. Sugikawa, T. Shiraki, Y. Tsuchiya, S. Haraguchi, K. Sada, S. Shinkai*
DOI: 10.1080/10610278.2010.521837

[16]

Single-crystal Structure of Porphyrin Bicapped with Trimethyl-β-cyclodextrins: A Novel Dye-oriented Material
Chem. Lett., 40, 99-101 (2011)
Y. Tsuchiya*, A. Yamano, T. Shiraki, K. Sada, S. Shinkai*
[Selected as Editor’s Choice.]
DOI: 10.1246/cl.2011.99

[15]

Thermo- and Solvent-Responsive Polymer Complex Created from Supramolecular Complexation between a Helix-Forming Polysaccharide and Cationic Polythiophene
J. Am. Chem. Soc, 132, 13928-13935 (2010)
T. Shiraki, A. Dawn, Y. Tsuchiya, S. Shinkai*
DOI: 10.1021/ja1067349

[14]

Ratiometric Fluorescent Sensor for 2,4,6-Trinitrotoluene Designed Based on Energy Transfer between Size-different Quantum Dots
Chem. Lett, 39, 156-158 (2010)
T. Shiraki, Y. Tsuchiya, S. Shinkai*
DOI: 10.1246/cl.2010.156

[13]

A Polysaccharide-Based Container Transportation System Powered by Molecular Motors
Angew. Chem. Int. Ed., 49, 724-727 (2010)
Y. Tsuchiya, T. Komori, M. Hirano, T. Shiraki, A. Kakugo, T. Ide, J.-P. Gong, S. Yamada, T. Yanagida*, S. Shinkai*
[Selected as Newsworthy Paper.]
DOI: 10.1002/anie.200904909

[12]

Alignment of Polysaccharide-SWNT Composites by Metal-Ligand Interactions
Chem. Lett., 38, 812-813 (2009)
Y. Tsuchiya, S. Haraguchi, K. Sugikawa, T. Shiraki, K. Kaneko, S. Shinkai*
DOI: 10.1246/cl.2009.812

[11]

On the Helical Motif of the Complexes Created by Association of Helix-Forming Schizophyllan (SPG) and Helix-Forming Polythiophene Derivatives
Chem. Eur. J., 15, 11221-11228 (2009)
S. Haraguchi, Y. Tsuchiya, T. Shiraki, K. Sugikawa, K. Sada, S. Shinkai*
DOI: 10.1002/chem.200901003

[10]

Control of polythiophene redox potentials based on supramolecular complexation with helical schizophyllan
Chem. Commun, 45, 6086-6088 (2009)
S. Haraguchi, Y. Tsuchiya, T. Shiraki, K. Sada, S. Shinkai*
DOI: 10.1039/b910085g

[9]

Quantum Dots Arrangement and Energy Transfer Control via Charge-Transfer Complex Achieved on Poly(Phenylene Ethynylene)/Schizophyllan Nanowires
Chem. Asian J., 4, 1434-1441 (2009)
T. Shiraki, S. Haraguchi, Y. Tsuchiya, S. Shinkai*
DOI: 10.1002/asia.200900175

[8]

Photocurrent generators derived from non-covalently assembled soft-matter molecular system
J. Oleo Sci., 56, 603-610 (2007)
Y. Tsuchiya, T. Arimura*, N. Minami, M. Tashiro, M. Tachiya

[7]

13C NMR longitudinal relaxation time studies of a molecular tweezers derived from a calixarene-porphyrin conjugate
J. Oleo Sci., 56, 155-158 (2007)
T. Arimura*, T. Nishioka, Y. Suga, S. Kumamoto, Y. Tsuchiya, T. Yamaguchi, M. Tachiya

[6]

Carbon-13 NMR longitudinal relaxation time study of an ionophoric 1,3-alternate-shaped calix[4]arene ester
J. Oleo Sci., 55, 75-78 (2006)
T. Arimura*, T. Nishioka, S. Kumamoto, Y. Tsuchiya, T. Yamaguchi, M. Tachiya

[5]

Sodium-23 NMR studies of sodium ion ensembles with a 1,3-alternate-shaped calix[4]arene
J. Oleo Sci., 55, 71-74 (2006)
T. Arimura*, T. Nishioka, S. Kumamoto, Y. Tsuchiya, T. Yamaguchi, M. Tachiya

[4]

Photocurrent-Boosting by Intramembrane Electron Mediation between Titania Nanoparticles Dispersed into Nafion-Porphyrin Composites
Chem. Mater., 17, 4018-4022 (2005)
A. Ikeda*, Y. Tsuchiya, T. Konishi, S. Ogasawara, J. Kikuchi

[3]

A photocurrent-generator utilizing a polyelectrolyte as a matrix of dyes
J. Mater. Chem., 14, 1128-1131 (2004)
Y. Tsuchiya, A. Ikeda*, T. Konishi, J. Kikuchi

[2]

Improvement of Quantum Yields for Photoinduced Energy/Electron Transfer by Isolation of Self-Aggregative Zinc Tetraphenyl Porphyrin-Pendant Polymer Using Cyclodextrin Inclusion in Aqueous Solution
J. Phys. Chem. B, 107, 11261-11266 (2003)
T. Konishi, A. Ikeda*, M. Asai, T. Hatano, O. Ito*, Y. Tsuchiya, J. Kikuchi

[1]

Electrochemical Polymerization of Pyrrole-substituted Tetrathiafulvalenyl-thiol, sulfone, and disulfide
Electrochemistry, 70, 584-586 (2002)
Y. Tsuchiya, H. Fujihara*

Proceeding

[2]

Photocurrent generators derived from non-covalently assembled cyclodextrin nano-system.
J. Photopolym. Sci. Technol.(Proc. 24th International Conference of Photopolymer Science and Technology), 20, 533-538 (2007) (Chiba, Japan).
T. Arimura, Y. Tsuchiya, M. Tashiro, M. Tachiya

[1]

Photocurrent generations derived from non-covalently assembled porphyrin conjugate nano-system.
J. Photopolym. Sci. Technol.(Proc. 24th International Conference of Photopolymer Science and Technology), 19, 409-411 (2006) (Chiba, Japan).
Y. Tsuchiya, T. Arimura, M. Tachiya

総説、解説、著書

[5]

“Dye Inclusion Single Crystals; Preparations, Structures and Functions”
Chapter 11 in “Cyclodextrins: Synthesis, Chemical Applications and Role in Drug Delivery”, F. G. Ramirez (Ed)
Nova Science Publishers: New York, USA, 2015 (in press)
ISBN: 978-1-63482-788-1

Y. Tsuchiya

[4]

「多糖を利用したナノ人工コンテナ輸送システムの開発」
セラミックス（Ceramics Japan），2014年，49巻，No.5，pp 406-410．
土屋 陽一

[3]

「らせん形成多糖をテンプレートとした光活性プラズモニック金属ナノ粒子」
コロイドおよび界面化学部会ニュースレター（Colloid & Interface Commun.），2013年，38巻，No.4，pp 12-15．
土屋 陽一

[2]

“New nanomaterial created through complexation with helix-forming polysaccharides”
「らせん多糖と機能性材料の複合化によるナノマテリアルの開発」
月刊ファインケミカル，2011年，40巻，pp7-14．
白木 智丈，土屋 陽一，新海 征治

[1]

“Advanced Functionalities of Macromolecular Assemblies Designed by Molecular Recognition”
「分子認識を活用する高分子組織体のデザインと高次機能の創出」
科学と工業，2010年，84巻，pp367-375．
土屋 陽一，白木 智丈，新海 征治

受賞

第30回　シクロデキストリンシンポジウムポスター賞（2013年9月）

第9回　積水化学　自然に学ぶものづくり　研究助成プログラム　奨励賞（2010年10月）

依頼・招待講演

[8]

「シクロデキストリン－金属ポルフィリン包接錯体結晶の単結晶Ｘ線構造解析」
分子・物質合成プラットフォーム平成25年度シンポジウム，2014年3月11日

[7]

第11回 積水化学 自然に学ぶものづくりフォーラム，2013年10月17日

[6]

「分子認識を利用したナノテクノロジー　～生物をお手本にしたものづくり～」
崇城大学工学部ナノサイエンス学科特別講演会，2013年6月27日

[5]

「高次機能組織体によるナノ材料・ナノシステムの構築」
福岡新テクノロジー創成シンポジウム，2012年11月27日

[4]

「高次分子認識を駆使したナノシステムとナノ材料」
第4回ネイチャーテクノロジー研究会幹事会，2012年7月11日

[3]

「バイオミメティック包接複合体の単結晶」
日本化学会第92春季年会　Advanced Technology Program，2012年3月25日

[2]

「生体分子モーターを用いた人工コンテナ輸送システムの動作制御に関する研究」
第9回 積水化学 自然に学ぶものづくりフォーラム，2011年10月17日

[1]

「産官学協働による共同研究事例について: 撥油界面の光パターニング技術の開発」
九州大学G-COE 第４回産学連携セミナー，2011年8月3日

特許

[3]

特許5561780「包接錯体結晶材料」

[2]

特許5561780「カリックスアレーン誘導体を用いる希土類金属の検出法」

[1]

特開2005-251426「光電変換素子を用いた色素量の測定方法」

学会発表

国際学会

[6]

Supramolecular Dye Inclusion Single Crystals Created from Cyclodextrins and Porphyrin
the 2012 International Symposium on Macrocyclic and Supramolecular Chemistry, ISMSC-7, Otago, Dunedin, New Zealand, February, 2012.
Y. Tsuchiya, T. Shiraki, T. Matsumoto, K. Sugikawa, K. Sada, A. Yamano, S. Shinkai

[5]

Artificial Container Transportation System (Oral)
The 2010 International Chemical Congress of Pacific Basin Societie, Honolulu, Hawaii, USA, December, 2010.
Y. Tsuchiya, T. Komori, T. Shiraki, A. Kakugo, J.-P. Gong, T. Yanagida, S. Shinkai

[4]

Novel Polysaccharide-Based Container Transportation System Powered by Molecular Motors
The 5th International Symposium on Macrocyclic & Supramolecular Chemistry, Nara, Japan, June, 2010.
Y. Tsuchiya, T. Komori, T. Shiraki, T. Yanagida, S. Shinkai

[3]

Container Transportation Model System by Using Polysaccharide
The 1st FAPS Polymer Congress, Nagoya, Japan, September, 2009.
Y. Tsuchiya, T. Komori, M. Hirano, T. Shiraki, A. Kakugo, T. Ide, J.-P. Gong, S. Yamada, T. Yanagida, S. Shinkai

[2]

Accumulation of Histidine Tagged Proteins to Sugar-SWNT Composites
The 4th LSW Symposium on Soft & Wet Matter, Sapporo, Japan, January, 2009.
Y. Tsuchiya, S. Yamada, S. Shinkai

[1]

Accumulation of Histidine Tagged Proteins to Sugar-SWNT Composites Bearing Metal Ligands
International Symposium on Molecular and System Life Sciences, Kobe, Japan, December, 2008.
Y. Tsuchiya, Sunao Yamada, Seiji Shinkai